ࡱ> vxstu bjbj x&oo  OOOOOcK"K"K"K"$o"$c("L""""###''''''')+d'O#####'Z$OO""'Z$Z$Z$#jO"O"'Z$#'Z$Z$&OO1'0lK",$.&'$'0(', ,Z$ ,1'Z$1'BOs'###cc' $cc' :    ϲʿ¼ WEST INDIA ROYAL SOCIETY OF CHEMISTRY WEST INDIA SECTION http://www.rsc.org In association with DEPARTMENT OF CHEMISTRY, IIT TOPICS IN GREEN CHEMISTRY Inauguration by Professor Nandkishore, HOD, Chemistry Department, IIT Bombay GUEST SPEAKERS DR.PETER LICENCE, University of Nottingham Ionic liquids in -vacuo Professor G.D.Yadav, Director, Institute of Chemical technology (ICT), Mumbai Green Chemistry & Sustainability Dr.Anilkumar, NCL Physical Chemistry of Organic reactions in Water & Ionic Liquids Sunil Joshi, NCL SUPERCRITICAL WATER Poster presentation by Ph.D.Students 12.30 to 1.30 Special Lunch 1.00. p.m. ALL ARE INVITED VENUE Department Seminar, IIT MUMBAI Date: Saturday 6th February Time: 9.30 a.m. to 12.00 noon RSVP: nandk@chem.iitb.ac.in ϲʿ¼ WEST INDIA:  HYPERLINK "mailto:rgopalan@vsnl.com" rgopalan@vsnl.com, Mobile +91 9820295206  HYPERLINK "http://www.mymailsignature.com/?partner=ZGzeb001" \t "_blank"  INCLUDEPICTURE "http://www.mymailsignature.com/sig.jsp" \* MERGEFORMATINET  Physical Chemistry of Organic Reactions in water and Ionic Liquids Anil Kumar Physical Chemistry Division National Chemical Laboratory Pune 411008, India Email:  HYPERLINK "mailto:a.kumar@ncl.res.in" a.kumar@ncl.res.in Spectacular rate enhancement of Diels-Alder reactions in water and aqueous salt solutions originate as a result of enhanced hydrophobic packing or the solubility effect during the reaction. A quantitative criteria of measuring the hydrophobic effects will be discussed to enable us to understand the origin of forces responsible for such a rate enhancement in Diels-Alder and many other organic transformations. Importance of aqueous interface at on water Wittig reactions will be discussed to show that hydrophobic acceleration of reactions comprising on water reactants is fundamentally different from that for reactions with small non-polar solutes with a quantitative description of on water reactions. In view of the ionic liquids emerging as substitute to volatile organic compounds, some results will be presented on the role of friction in terms of viscosity of ionic liquids in controlling the kinetics of bi-molecular intermolecular Diels-Alder reactions. In the case of an intramolecular Diels-Alder reaction, the results will be analyzed on the basis of the current theoretical models and their failure to account for the observed trends will be discussed in terms of effective viscosity or microviscosity. The rates of the reaction decrease with the increasing viscosity of the ionic liquids for both types of Diels-Alder reactions. As evident from the anionic effect, the solute-solvent specific interactions play a role in governing the kinetics of the reaction. It will be proposed that the solvent microviscosity, rather than the bulk macroscopic viscosity, should be the criteria for selecting the ionic liquids as reaction media. 9Peyz     ûzm`SE:Eh$ 5>**<h$ 5>*B*phhm}h$ 5B*phhWh$ 5B*phh'h$ 5B* phh h$ 5B* CJ$phh h$ 5B*CJph h$h$ h$ B*phh$ 5B*phh$ B*CJphhmFB*phh[hmFB*mH ph33sH hm}hmFB*phh hM+B*phhM+B*ph33jh hm}B*Uph339PQdeyz    ? Y n $a$gd$ $a$gd$ ]gd$ $]a$gd$ ]gd$  > ? 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