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Water at interfaces Faraday Discussion

20 - 22 September 2023, London, United Kingdom


Introduction
There are major water-related challenges that require enhanced molecular-level understanding and description of water at interfaces, to relate that understanding to macroscopic phenomena in aqueous systems, and then ultimately utilize or control those phenomena. Interfacial water is crucial for disciplines as diverse as atmospheric science, geochemistry, energy science, water purification/desalination, and biology.

This Faraday Discussion aims to combine different approaches, both experimental and theoretical, to further our understanding of the fundamental properties of water at interfaces. Such insights are expected to have important implications for chemistry, biology and potentially medicine; key sustainable technologies such as filtration, desalination, and photocatalytic water splitting; as well as modelling of processes in atmospheric chemistry and physics.

Themes

Dynamics and Nano-Rheology of Interfacial Water
While we have made progress in understanding the static properties of interfacial water, water is in motion for many naturally occurring phenomena (raindrops falling, rivers flowing, etc.) and technological applications (water traversing membranes in water purification, desalination). At the nanoscale, the description of water in terms of its macroscopic properties (density, viscosity, etc.) breaks down, and novel concepts and experimental approaches are needed to further our understanding.

Electrified / Charged Aqueous Interfaces
Interfaces are often charged, because of the intrinsic charge of the material interface and membrane interface, as well as the emergence of the counter charge as a response of the water pH. In electrochemistry, charge is applied to drive molecular orientation, charge transfer, and chemical transformation. These interfaces induce ion condensation, generating the electrical double layer – Stern layer and diffuse layer Although it is evident that the molecular organization at electrochemical, electrified interfaces determines the chemistry occurring at these interfaces, the description of these processes still occurs at a mean-field level. Is that sufficient?

Ice Interfaces
Ice is omnipresent in the environment and constitutes an entirely different aqueous interface than that of the liquid. Or does it? The ice-vapor interface starts to be disordered – with reportedly liquid-like properties – above 200 K, much lower than the melting point of bulk ice. This disordered layer is often called the quasi-liquid layer. This quasi-liquid layer plays a critical role in the lubrication of ice surface, gas uptake by ice, and growth of aerosols affecting climate change. Furthermore, ice nucleation process such as heterogeneous ice nucleation which is bound to the material interface affects the biological functions of animals in the cold sea as well as technology aiming at controlling friction of ice. 

Soft Matter-Water Interface
Soft matter ranges from the biological membrane interface to the polymer interface. Biological interfaces often are unstable without water; water drives the self-assembly of biological structures, and through the interaction with interfacial water, their biological function emerges. Polymer interfaces allow control over the hydrophobicity/hydrophilicity, and the variation of the interfacial water properties e.g. pH and temperature, alters the formation of polymers, making polymer materials useful for drug delivery and coating. A particularly interesting soft matter-water interface is the interface that originates from liquid-liquid phase separation in aqueous solutions of polymers and intrinsically disordered proteins. All these interfaces have in common that molecular-level insights into the interactions of these interfaces with interfacial water remain unclear.

Speakers
Rich Saykally, (Introductory lecturer), University of Berkeley, United States

Richard Saykally is a Professor of the Graduate School at the University of California-Berkeley. Born in Rhinelander, Wisconsin and educated at UW-Eau Claire and UW-Madison, Saykally has been a professor at the University of California, Berkeley since 1979. He and his students have pioneered important advances in spectroscopy, including velocity modulation spectroscopy of ions, terahertz laser vibration-rotation-tunneling spectroscopy of clusters, infrared photon counting spectroscopy, cavity ringdown spectroscopy, and X-ray spectroscopy of liquid microjets. These have permitted the first detailed study of important textbook molecules, including the hydronium (H3O+), hydroxide (OH-) and ammonium (NH4+) ions, as well as small water clusters and carbon clusters. 

Recent work includes the spectroscopic determination of a universal water force field via the study of water clusters, the development of femtosecond nonlinear optical molecular imaging methods applied to single nanowire lasers and biological systems, femtosecond UV SHG/SFG studies of aqueous interfaces, and soft X-ray spectroscopy of liquids and liquid surfaces.

A co-author of over 400 publications that have been cited over 50,000 times (H index > 100), the recipient of over 78 honors and awards from 15 different countries, Saykally is a member of the National Academy of Sciences and the American Academy of Arts and Sciences, and has received the E.O. Lawrence Award in Chemistry from the U.S. Department of Energy, the Hinshelwood Lectureship from Oxford University, the Inaugural International Solvay Chair in Chemistry from the Solvay Institutes of Belgium, the Peter DeBye Award in Physical Chemistry from the ACS, the J.C. Bose Lectureship from IACS-Kolkata, and the Faraday Lectureship Prize from the UK °ÄÃÅÁùºÏ²Ê¿ª½±¼Ç¼. He is a UC-Berkeley Distinguished Teacher, and has been active at the national level in science education. Over 150 students and postdocs have trained under his direction, many of whom hold prominent positions in academic, government, and industrial institutions.


Giulia Galli (Closing remarks), University of Chicago, United States

Giulia Galli is the Liew Family professor of Electronic Structure and Simulations in the Pritzker School of Molecular Engineering and the Department of Chemistry at the University of Chicago. She also holds a Senior Scientist position at Argonne National Laboratory, where she is the director of the Midwest Integrated Center for Computational Materials
She is an expert in the development of theoretical and computational methods to predict and engineer material and molecular properties using quantum simulations.
Prior to joining UChicago, she was Professor of Chemistry and Physics at UC Davis (2005-2013) and the head of the Quantum Simulations group at the Lawrence Livermore National Laboratory (LLNL, 1998-2005).
She is an elected member of the US National Academy of Sciences, the American Academy of Arts and Science and the International Academy of Quantum Molecular Science. Her recognitions include the Rahman Prize in Computational Physics and the David Adler Award in Materials Physics from the American Physical Society, the Theory Award from the Materials Research Society, the Feynman Nanotechnology Prize in Theory and the Tomassoni-Chisesi prize. In addition she recently received the Lifetime Achievement Award by the Italian Scientists and Scholar of North America Foundation.
 


Ellen Backus, University of Vienna, Austria

  Ellen Backus is professor for physical chemistry at the University of Vienna since 2018. Her research
focuses on the molecular structure and (ultrafast) dynamics of various aqueous interfaces by using surface-specific vibrational spectroscopy. She obtained her PhD in 2005 at the Leiden University. After postdoctoral research at the University of Zurich and at AMOLF in Amsterdam, she started in 2012 as a groupleader at the Max Planck Institute for polymer research in Mainz.


Stephen Cox, University of Cambridge, United Kingdom

I obtained my PhD in 2014 from University College London under the guidance of Angelos Michaelides, where I used molecular simulations to further our understanding of heterogeneous ice nucleation. From 2015-2017, I undertook post-doctoral research with the late Phill Geissler at Lawrence Berkeley National Laboratory, in which I used theory and simulation to understand ion solvation, both in bulk and interfacial water. In 2017, I was awarded a research fellowship from the Royal Commission for the Exhibition of 1851, which I held in Cambridge. Since October 2021, I have held a Royal Society University Research Fellowship in the Yusuf Hamied Department of Chemistry, University of Cambridge. My research focuses on trying to understand how solution environments affect the structure and dynamics of materials.


Ulrike Diebold, TU Wien, Austria

Ulrike Diebold is a professor of surface physics at the Vienna University of Technology (TU Wien) in Vienna, Austria.  She conducts research in experimental surface science with an emphasis on metal oxide surfaces.  She is particularly interested in the atomic-scale properties of these complex materials, and in unraveling their (defect)structure/reactivity relationship.  The main tool, Scanning Probe Microscopy, is complemented by area-averaging surface spectroscopies and first-principles calculations.  Her research on fundamental interactions between water and oxide surfaces is supported by an ERC Advanced Grant.


Ying Jiang, Peking University, Beijing, China

Ying Jiang is a Boya Distinguished Professor of Peking University. He received his PhD from Institute of Physics, Chinese Academy of Sciences (CAS) in 2008. After working as a Postdoctoral Associate in University of California, Irvine (2008-2010), he joined International Center for Quantum Materials, Peking University as a tenure-track assistant professor, and was promoted to a full professor in 2018. He is the founding director of Research Center for Light-Element Advanced Materials of Peking University. Jiang serves on the Editorial Boards or Editorial Advisory Boards of Research, Journal of Physical Chemistry, Journal of Chemical Physics, Advanced Quantum Technologies, Chemical Physics, Chinese Physics Letters, etc.
 
Jiang’s research fields are condensed matter physics and chemical physics. His research achievement covers from the innovative development of scanning probe microscopy/spectroscopy to the application of those techniques to probe and manipulate single molecules, nanostructures and low-dimensional materials with atomic precision. Recently, Jiang has opened up new possibility of understanding the structure and dynamics of water and ion hydration at interfaces with H-sensitive and non-invasive scanning probe microscopy. He has published over 70 peer-reviewed papers, including 3 in Science, 5 in Nature, and 10+ in Nature Journals. His research works were selected twice as Top-ten Science Advances in China (2016, 2018).
 
Selected awards include Distinguished Young Scholars of NSFC (2017), Tan Kah Kee Young Scientist Award (2018), Science and Technology Award for Chinese Youth (2018), Leading Innovative Talent in Science and Technology (2019), Fellow of American Physical Society (2019), Nishina Asia Award (2020), AAA Robert T. Poe Prize (2020), Xplorer Prize (2022).


Monica Olvera de la Cruz, Northwestern University, United States

Monica Olvera de la Cruz obtained her Ph.D. in Physics from Cambridge University, UK, in 1985. She joined Northwestern University in 1986, where she is the Lawyer Taylor Professor of Materials Science & Engineering, Professor of Chemistry, and by courtesy, Professor of Physics and Astronomy and Chemical & Biological Engineering. She is the Director of the Center for Computation and Theory of Soft Materials. From 1995-97 she was a Staff Scientist in the Commissariat a l’Energie Atomique, Saclay, France, where she also held visiting scientist positions in 1993 and 2003. She has developed theoretical models to determine the thermodynamics, statistics, and dynamics of soft materials including multicomponent solutions of heterogeneous synthetic and biological molecules, and molecular electrolytes. She is a member of the American Philosophical Society, the National Academy of Sciences (NAS), the American Academy of Arts and Sciences, and a Fellow of the American Physical Society (APS). She has served in the Advisory Committees of the Department of Energy Basic Energy Science Program (2012-21) and the NSF Mathematical and Physical Science Directorate (2005-09), as well as in various committees of the National Research Council (NRC) including the Board of Physics and Astronomy (2009-15).  She serves in the scientific advisory committee of the Max Planck Institute for Polymer Research, and ESPCI (École supérieure de physique et de chimie industrielles de la Ville de Paris). She has been Senior Editor for the ACS Central Science and a member of the PNAS editorial board, and a member of the Board of Trustees of the Gordon Research Conferences (2019-27).
 


  • Nikita Kavokine Flatiron Institute, United States
  • Adam Willard MIT, United States

Abstract Submission

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Abstract submission is now closed.
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Poster abstracts

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Submit your poster abstract by 10 July 2023. Posters are displayed throughout the meeting, both in-person and online. A poster prize will be awarded to the best poster presented by a student at the conference.

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A selection of sponsorship opportunities is available for companies who would like to promote their activities at the 2023 Faraday Discussion series.
 
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